A transactional error concerns the content of the transaction, for example an essential characteristic of the property that the buyer wrongly assumes. Under section 871 ABGB you can avoid the contract for such an error, but only under narrow conditions. The error must have been caused by the other party, must obviously have been apparent to them from the circumstances or must still have been clarified in time.
The error is essential if the contract would not have been concluded, or not on those terms, without it. If the error concerns only a secondary point, it does not lead to annulment but at most to an adjustment of the contract. A mere error in the motive, which lies outside the content of the transaction, does not in principle entitle you to avoidance.
The legal consequence of successful avoidance is the annulment of the contract from the outset. The performances are restored, the buyer returns the property and receives the purchase price. How the error differs from a material defect is covered in the post on the warranty for hidden defects.